2-Isopropyl-5-methylcyclohexyl 5-acetoxy-1,3-oxathiolane-2-carboxylate
نویسندگان
چکیده
In the title compound, C(16)H(26)O(5)S, the oxathiol-ane ring adopts an envelope conformation, with the S atom 0.793 (3) Å out of the mean plane of the remaining four atoms. The cyclo-hexane ring of the menthol fragment adopts an almost ideal chair conformation, with all substituents in the equatorial positions. In the crystal, relatively strong, short and linear C-H⋯O hydrogen bonds link the mol-ecules into the chains along [100] direction. The chains are packed into the crystal structure by means of weak dispersive inter-actions. Inter-molecular C-H⋯S inter-actions are also observed.
منابع مشابه
2-Isopropyl-5-methylcyclohexyl quinoline-2-carboxylate
In the title compound, C20H25NO2, the cyclo-hexyl ring adopts a slightly disordered chair conformation. The dihedral angle between the mean planes of the quinoline ring and the carboxyl-ate group is 22.2 (6)°. In the crystal, weak C-H⋯N inter-actions make chains along [010].
متن کامل(R p)-2-Isopropyl-5-methylcyclohexyl isopropyl(phenyl)phosphinate
The title compound, C(19)H(31)O(2)P, features a distorted tetra-hedral P atom that bonds to the phenyl ring, isopropyl and 2-isopropyl-5-methyl-cyclo-hexyl groups, and is determined as having an R(p) configuration. A chair conformation is observed for the cyclo-hexyl ring. In the crystal, mol-ecules are linked into chains running along the a axis by weak inter-molecular C-H⋯O hodrogen bonds.
متن کامل2-Isopropyl-5-methylcyclohexyl cyclohexyl(phenyl)phosphinate
In the title mol-ecule, C(22)H(35)O(2)P, the two cyclo-hexyl rings exhibit chair conformations. In the crystal, mol-ecules related by translation along the b axis are linked by the weak inter-molecular C-H⋯O hydrogen bonds.
متن کامل2-Isopropyl-5-methylcyclohexyl diphenylphosphonamidate
In the title compound, C(22)H(30)NO(2)P, the P atom has an irregular tetra-hedral geometry. In the crystal, mol-ecules are connected by N-H⋯O hydrogen-bonding inter-actions, giving rise to a chain along the b axis. The phenyl ring of the anilino group is twisted by 77.40 (16)° relative to the other phenyl ring. The absolute configuration of phospho-rus is S(p).
متن کاملN-tert-Butyl O-2-isopropyl-5-methylcyclohexyl phenylphosphonamidate
In the title compound, C(20)H(34)NO(2)P, the P atom has an irregular tetra-hedral environment and exhibits S(p) chirality. In the crystal, weak inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into chains extending in [010].
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009