2-Isopropyl-5-methyl­cyclo­hexyl 5-acet­oxy-1,3-oxathiol­ane-2-carboxyl­ate

نویسندگان

  • Grzegorz Dutkiewicz
  • C. S. Chidan Kumar
  • H. S. Yathirajan
  • A. N. Mayekar
  • Maciej Kubicki
چکیده

In the title compound, C(16)H(26)O(5)S, the oxathiol-ane ring adopts an envelope conformation, with the S atom 0.793 (3) Å out of the mean plane of the remaining four atoms. The cyclo-hexane ring of the menthol fragment adopts an almost ideal chair conformation, with all substituents in the equatorial positions. In the crystal, relatively strong, short and linear C-H⋯O hydrogen bonds link the mol-ecules into the chains along [100] direction. The chains are packed into the crystal structure by means of weak dispersive inter-actions. Inter-molecular C-H⋯S inter-actions are also observed.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

2-Isopropyl-5-methyl­cyclo­hexyl quinoline-2-carboxyl­ate

In the title compound, C20H25NO2, the cyclo-hexyl ring adopts a slightly disordered chair conformation. The dihedral angle between the mean planes of the quinoline ring and the carboxyl-ate group is 22.2 (6)°. In the crystal, weak C-H⋯N inter-actions make chains along [010].

متن کامل

(R p)-2-Isopropyl-5-methyl­cyclo­hexyl isoprop­yl(phen­yl)phosphinate

The title compound, C(19)H(31)O(2)P, features a distorted tetra-hedral P atom that bonds to the phenyl ring, isopropyl and 2-isopropyl-5-methyl-cyclo-hexyl groups, and is determined as having an R(p) configuration. A chair conformation is observed for the cyclo-hexyl ring. In the crystal, mol-ecules are linked into chains running along the a axis by weak inter-molecular C-H⋯O hodrogen bonds.

متن کامل

2-Isopropyl-5-methyl­cyclo­hexyl cyclo­hex­yl(phen­yl)phosphinate

In the title mol-ecule, C(22)H(35)O(2)P, the two cyclo-hexyl rings exhibit chair conformations. In the crystal, mol-ecules related by translation along the b axis are linked by the weak inter-molecular C-H⋯O hydrogen bonds.

متن کامل

2-Isopropyl-5-methyl­cyclo­hexyl diphenyl­phospho­namidate

In the title compound, C(22)H(30)NO(2)P, the P atom has an irregular tetra-hedral geometry. In the crystal, mol-ecules are connected by N-H⋯O hydrogen-bonding inter-actions, giving rise to a chain along the b axis. The phenyl ring of the anilino group is twisted by 77.40 (16)° relative to the other phenyl ring. The absolute configuration of phospho-rus is S(p).

متن کامل

N-tert-Butyl O-2-isopropyl-5-methyl­cyclo­hexyl phenyl­phospho­namidate

In the title compound, C(20)H(34)NO(2)P, the P atom has an irregular tetra-hedral environment and exhibits S(p) chirality. In the crystal, weak inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into chains extending in [010].

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009